The terminology sensitization, which is generally used to discuss intergranular corrosion cracking behaviors, has different metallurgical meanings depending on intergranular corrosion test methods such as strauss, electrochemical potentiokinetic reacitivationepr and wackenroeder test. The mechanism of scc is shown as a simple representation in figure 1. In this chapter, the conditions for the occurrence of scc are first introduced. Brown chemistrydepartment theamericanuniversity washington,d. It has been shown that, for some materials, fine pitting is needed to start the activity. Mechanical engineering assignment help, polythionic acid stress corrosion cracking, in naphtha hydrotreating unit, does feedeffluent heat exchangers require passivation to avoid polythionic acid stress corrosion cracking. Further progress is then a process alternating between corrosion and mechanical cracking. Assessing stress corrosion cracking risks on stainless. If the cracking has been correctly diagnosed as chloride stress corrosion cracking, and the problem is confined to small drain, flush fittings, etc. The alloys 321 and 347 are particularly useful under conditions which cause polythionic acid stress corrosion of nonstabilized austenitic stainless steel, such as alloy 304. Prevents polythionic acid stress corrosion cracking. What are the industrial practices being followed in. Ambient temperature stresscorrosion cracking of sensitized. Shuo weng, yu hui huang, fu zhen xuan, ling hua luo.
Presence of cr, carbon, exposure temperatures and presence of polythionic acids play an important role in stress corrosion cracking. Heat treatment method for reducing polythionic acid stress. Stress corrosion cracks propagate over a range of velocities from about 103 to 10 mmh, depending upon the combination of alloy and environment involved. This paper discusses ae results of activepath dissolutiontype scc of austenitic stainless steel in chloride solution and fused salt, fluoride and polythionic acid solutions, brass. The tower provided a caustic solution naoh to remove hcl from the stream, before the latter was directed to a burner. Pascc polythionic acid stress corrosion cracking oil. Polythionic acid is an oxoacid which has a straight chain of sulfur atoms and has the chemical formula snso3h2.
This means that all environments do not cause scc on all of the alloys. Their geometry is such that if they grow to appropriate lengths they may reach a critical size that results in a transition from the relatively slow crack. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. Stress corrosion cracking of sensitized type 304 steel in low temperature borated water has been observed. Stress corrosion cracking of ring type joint of reactor. The pipeline was used to carry a stream of gaseous hydrocarbons containing hydrochloric acid hcl into a reaction tower. This standard is directed toward preventing stress corrosion cracking scc caused by polythionic acid pta that can be formed by reaction of oxygen and water with sulfide corrosion products i. A bent nicu monel 400 alloy tube, which operated as part of a pipeline in a petrochemical distillery installation, failed by throughthickness cracking. Polythionic acid is formed by the reaction of sulphide scale, oxygen and water. Chemical studies of polythionic acid stresscorrosion cracking. Stress corrosion cracking behavior of materials intechopen. Software for the modeling and prediction of naphthenic acid corrosion nac 5. Pdf stress corrosion cracking damages researchgate.
Polythionic acid stress corrosion cracking pascc is an affliction of many refineries processing sulfur containing feedstocks, and since that is the norm these days, most refiners reduce their susceptibility to pascc by selecting resistant alloys orby neutralizing exposed surfaces during shutdowns. This failure mechanism is possible from both inside and outside of a tube. This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon. This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be vulnerable under certain conditions.
Api rp 571 damage mechanisms affecting fixed equipment. Department of energys office of scientific and technical information. Exposure of nonstabilized austenitic stainless steel pipe to temperatures in the sensitizing range will cause the precipitation of chromium carbides at grain boundaries. The compounds of n polythionic acid stress corrosion cracking during shutdown of refinery equipment. Polythionic acid stress corrosion cracking in heater pipes. The most common fluid that causes inter granular stress corrosion cracking igscc in petrochemical plants and refineries is polythionic acid. Overview of polythionic acid stress corrosion cracking pascc. Ctlpolythionic stress corrosion cracking of stainless. To screen candidate materials of construction for resistance to stress corrosion cracking, racks of stressed. It is found that the degradation mechanism of the shift reactor was due to the polythionic acid stress corrosion cracking. Polythionic acid stress corrosion cracking pascc is a type of intergranular stress corrosion that affects sensitized stainless steels in refineries processing feedstocks containing sulphur. On the other hand, polyesters are readily degraded by acids, and scc is a likely failure mechanism. Polythionic acid stress corrosion cracking, mechanical. This failure mechanism is possible from both inside and outside of a tube, depending on the sulfur source.
Based on this analysis the leaks were caused by cracks that initiated on the id surface. The cracks are intergranular and narrow with no significant branching. This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be. Polythionic acid stress corrosion cracking deterioration mechanisms heaters used in hydrodesulfurization, hydroforming, hydrocracking, and similar processes often have austenitic stainless steel tubes and usually process reactor feed or recycled. Testing laboratory testing can be carried out according to nace tm0177 5% nacl and 0. This failure mechanism is possible from both inside and outside of a tube, depending on the. Precipitation reactions that occur in inconel alloy 600 were studied and correlated with corrosion behavior in nitric acid and stress corrosion cracking scc susceptibility in polythionic acid and sodium hydroxide. Polythionic acid stress corrosion cracking pascc is a type of intergranular stress corrosion that affects. Both austenitic and straight chromium grades of stainless steels can be attacked by polythionic acid. Stresscorrosion cracking, materials performance and. Polythionic stress corrosion cracking of stainless steel tube. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment.
Pdf polythionic acid corrosion in refinery hydroprocessors. This failure mechanism is possible from both inside and outside of a. Trithionic acid, tetrathionic acid are simple examples. Precipitation reactions in inconel alloy 600 and their. Results show that alloys 304 and 304l, in the solution. Stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Amine cracking is often severe on the molecular level but seemingly minor when externally observed on a metal surface such as a pipeline. Stress corrosion cracking scc is one of the most prevalent root causes of stainless steel failures in the refining industry.
It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Stress relaxation cracking of welded joints in thick sections. Michael j schofield bsc, msc, phd, mim, ceng, in plant engineers reference book second edition, 2002. Polythionic acid stress corrosion cracking oil refining pascc. This damage mechanism primarily affects standard and high carbon stainless steels.
Type 304l shares disadvantages of 304h it does sensitize at high temperature, however and can be susceptible to polythionic acid stress corrosion cracking during shut down, especially if the regenerator is water washed. The required tensile stresses may be in the form of directly applied stresses or in the form of residual. It has been shown that h 2 sinduced stress corrosion cracking attack is worst at temperatures around 80c 176f, but cracking can occur also at temperatures below 60c 140f. An article of manufacture exhibiting resistance to polythionic acid stress corrosion cracking consisting essentially of about 2024% chromium, about 9. When stainless steels are fully immersed, it is rare to see chloride stress corrosion cracking at temperatures below 60 c 150 f. Creep stress rupture polythionic acid cracking naphthenic acid corrosion ammonium chloride corrosion hcl corrosion oxidation caustic cracking caustic corrosion erosionerosion corrosion chloride stress corrosion cracking short term overheating stress rupture 885 embrittlement disimilar metal weld dmw cracking co2 corrosion fuel ash corrosion. Stress corrosion cracking issues in syngas plants that may.
In austenitic stainless steels, chloride scc is transgranular in nature and the cracks. Effects of sensitization and service fluid chemistry on polythionic acid stress corrosion cracking of 188 stainless steels authors eiki nagashima toyo engineering corp. Abstractlow temperature stress corrosion cracking of sensitized stainless steel, promoted by aqueous. In stabilized grades of austenitic steel, titaniumniobium are added which have stronger affinity to form carbides than chromium, thus protecting corrosion resistance.
Are there any methods that can be used to give a 100% picture of the status of the pipes whilst they are mounted in the heater. A hydrotest at 735 psi revealed numerous leaks in four tubes from a heater. Sulfur can come from feed stock, additives or fuels. Stress corrosion cracking susceptibility of stainless steels and nickelbase alloys in polythionic acids and acid copper sulfate solution. Any acid of the form h2sno6 having a chain of sulfur atoms. It requires a susceptible material and, depending on the material, sufficient levels of. Detailed metallurgical investigation was carried out to identify the probable causes that could. Bradley and others published alloy for resistance to polythionic acid stress corrosion cracking for hydroprocessing.
Stress relaxation cracking of welded joints in thick. Polythionic acid stress corrosion cracking pascc is an affliction of many. Api 571 damage mechanisms affecting fixed equipment in the. Cracking is the result of intense corrosion, concentrated by the tensile stress. It was further established that formation of polythionic acid due to presence of h 2 s in the process gas and h 2 0 in the system was responsible for initiation of scc in rtj components. Chemical and physical mechanisms of salt stresscorrosion cracking in the titanium 811 alloyh. Purely mechanical forms of cracking such as brittle failure and fatigue are not considered here. For practical purposes, it should be assumed that such acids can be formed by reaction of oxygen and water with oxidizable sulfur species sulfur, h2s, metal sulfides. Polythionic acid stress corrosion cracking ptascc is a type of intergranular stress corrosion that affects sensitized stainless steels in refineries processing feedstocks containing sulphur. A thermal stabilization treatment at 899 900 deg c for two hours is specified for increasing the corrosion resistance to intergranular corrosion and polythionic acid stress corrosion cracking. This standard is directed toward preventing stress corrosion cracking scc by polythionic acids that are formed by the reaction of sulfide corrosion products with oxygen and water. Polythionic acid stress corrosion cracking of type 310 stainless steel.
It can be prevented by alloying with ideal metals to prevent galvanic corrosion tendencies, reducing the amount of stresses present and modifying the environmental conditions that promote corrosion. Polythionic acid stress corrosion cracking deterioration. The most common fluid causing intergranular corrosion in hydrocarbon plants is polythionic acid. Alloy for resistance to polythionic acid stress corrosion. The environmental factors that increase the cracking susceptibility include higher temperatures, increased chloride content, lower ph, and higher levels of tensile stress. Stress corrosion cracking by krittin rattakham youtube. Polythionic acid is an oxoacid which has a straight chain of sulfur atoms and has the chemical formula s n so 3 h 2 n 2. Then, the stress corrosion cracking mechanism for various materials in conditions that are susceptible is discussed in detail. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Looking for online definition of pascc or what pascc stands for. Nov, 1990 the embodiments of the invention in which an exclusive property or privilege is claimed are defined as follows. This means in corrosive environments prone to scc, a smaller flaw size led the. Severe stress corrosion cracking was observed in the csbp ltd, western australia 304l unlagged stainless steel absorber column of a nitric acid plant after 15 years of plant operation.
Stress corrosion cracking of austenitic stainless steels can occur in refinery environments where chlorides or sulfidic scales exist. Oct 21, 2019 chloride stress corrosion cracking is a localized corrosion mechanism like pitting and crevice corrosion. Pdf stress corrosion cracking scc is the formation and growth of crack. Cracks that propagated through welds had a very brittle appearance, most probably due to the very poor creep rupture ductility of e34716 welds. The importance of a conjoint action of corrosion and stress as well as the nature of.
Polythionic stress corrosion cracking of stainless steel tube environment. It can cause corrosion of austenitic stainless steel radiant tubes during furnace cooldown if the furnace tubes have become sensitised in operation. Once the metal is sensitized, sulfide scale on the metal can react with moisture and air, typically during shutdowns, to form polythionic acid. Ae monitoring from various types of stress corrosion cracking scc has been conducted for the past 15 years in our laboratory. The probable role of low levels of chloride ions or sulfurcontaining ions is described including the relationship to polythionic acid cracking. Stress corrosion cracking scc may be defined as the delayed failure of alloys by cracking when exposed to certain environments in the presence of a static tensile stress.
Ugia 215 discussion 229 the diffusion of corrosion products in hotsalt stresscorrosion cracking of titaniumr. The astm standard for a376 and a 312 gives this treatment for the stabilzed grade austenitic stainless steels as a supplementary requirement without. These characteristics are consistent with stress corrosion cracking due to polythionic acids. Stress corrosion cracking susceptibility of stainless. Anybody aware of any ndt method that can be used to test for the presence of polythionic acid stress corrosion cracking in heatr pipes in a fired heater. Why does chloride stress corrosion cracking and pascc only. The mechanism of stress corrosion cracking scc involves a very complicated sequence of corrosion and fracture. All of the cracks observed were found underneath the coke deposits. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Pascc is listed in the worlds largest and most authoritative dictionary database of abbreviations and acronyms. Schematic view of stress corrosion cracking scc and corrosion fatigue cracking. Stress corrosion cracking facts and how to reduce the risk. However, to avoid scc in austenitic ss steels, exposure to conducive environment polythionic acid formation in presence of oxygenwaterchlorides along with metal sulfidesh2s to be reduced by adopting.
Feb 22, 2001 chloride induced cracking of stainless steels, caustic cracking of plain carbon steels, and ammonia damage to copper alloys are typical examples of this problem. The item was exposed to sulfur containing natural gas in a continuous flare. Cscc can attack highly resistant austenitic stainless steel. Polythionic acid is formed in the presence of sulfur, moisture and oxygen. Cracking mechanisms in which corrosion is implicated include stress corrosion cracking, corrosion fatigue, hydrogeninduced cracking and liquid metal embrittlement. The observed crack propaga tion is the result of the combined and synergistic interaction of mechanical stress and corrosion re actions. Intergranular and transgranular stress corrosion cracking of the aisi 316l stainless steel at polythionic acid environment 8. This phenomenon is usually an internal problem, occurring on the processexposed side of a piping run, vessel shell, exchanger bundle, heater tube. The cracking was found when rust stainingleaks were observed. Effects of sensitization and service fluid chemistry on. Cracking of sensitized stainless steels inspectioneering. Polythionic acid stress corrosion cracking deterioration mechanisms heaters used in hydrodesulfurization, hydroforming, hydrocracking, and similar processes often have austenitic stainless steel tubes and usually process reactor feed or recycled gas containing hydrogen sulfide and sulfur compounds. Pascc stands for polythionic acid stress corrosion cracking oil refining suggest new definition this definition appears somewhat frequently and is found in the following acronym finder categories.